openHAB uses the quartz Scheduler, unlike Gnu/Linux cron this allows to set the Seconds. Your Time cron expression has to be like
Time cron "0 */15 9-17 ? * MON-FRI"
0: at the full minute
*/15: every 15 minutes
9-17: 9 am to 5 pm (including, so last start will be 05:45 pm)
?: Day of month does not matter. You will have to use ? as you set the weekdays
*: Month does not matter
MON-FRI: from Monday to Friday