How to configure a rule condition on color state in OH3 - Web-Interface?

See

Rather misleadingly it mentions RGB, but you’ll note that the Item type state and commands are actually given in HSB.

Sure, if you mean within system hosted rules.

For example, in a DSL rule you can do
myColorItem.getStateAs(OnOffType)

If you’re talking about Web UI as per header, probably, but not with native methods.

What are you trying to do, what have you got so far?