Sorry, Karel, I indeed still need to document this somewhere.
What you need to do is to add this to your services.cfg:
org.eclipse.smarthome.voice:defaultVoice.<ttsId>=<voiceId>
e.g.
org.eclipse.smarthome.voice:defaultVoice.mactts=Anna
As you can see, you can define a default voice per TTS, so you can have multiple lines for different TTS.
Hope this helps!