openhab is the user that owns the file under /etc/openhab.
You can see that e.g. by using the command:
ls -ld /etc/openhab
which returns
drwxrwxr-x 15 openhab openhab 4096 Jan 30 12:26 /etc/openhab
first openhab is the user that owns the directory /etc/openhab
second openhab is the group that the user openhab is a member of.
Which command id you can see more information about the user openhab
id openhab
which returns
uid=110(openhab) gid=115(openhab) groups=115(openhab),5(tty),20(dialout),29(audio),112(bluetooth),997(gpio)
When you do that for user openhabian you should get a result similar to
uid=1000(openhabian) gid=115(openhab) groups=115(openhab),4(adm),5(tty),20(dialout),24(cdrom),27(sudo),29(audio),44(video),46(plugdev),60(games),100(users),105(input),109(netdev),112(bluetooth),999(spi),998(i2c),997(gpio),1000(openhabian),118(mosquitto)
openhab is the user the “service” openhab runs with. This is why files are owned by openhab so that the service can read the files and can write to directories ( /var/lib/openhab/… ).
The user openhabian is a user that is being used mainly for configuration and to easily get higher privileges with sudo command.
As you wrote that copying the files worked with OH2. Are you able to check the files/directories permissions you used with OH2 ?