Multiple Network Adapters

you didn’t mention the openHAB2 release that you are running, but in the latest Snapshot (1032) there is an option in PaperUI for this:

you can also set the IP Subnet in /etc/openhab2/services/runtime.cfg:

org.eclipse.smarthome.core.net.NetUtil:primaryAddress=172.16.13.0/24
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