Rule to enforce switch-on brightness level Fibaro RGBW

That’s a feature of your device.

Because your device reports it status periodically.
You openHAB Item gets set to 0 “prematurely” because you have got autoupdate enabled (by default). But then the real dimmer comes along and says “I’m not 0 (yet)”.
See “jitter” here -

If you look at your events.log, you will see the sequence.

Disabling autoupdate on your Item is a quick fix for commands from openHAB side - you didn’t say but I’m guessing the rule works fine if you control from outside of openHAB.

Otherwise, you’ll have to do something more elaborate, probably involving a brief timed lockout.