Did you stop OpenHAB first?
It needs to be running for the script to detect & uninstall any existing biinding.
No it was running, but i have it now.
I Have now Install an a another SD-Card the Raspbian and after the openHAB 2.5.0.M2 Milestone Build
And now is the Z-Wave Binding Version - 2.5.0.M2 and under Supported Things is now the Fibaro 223 to 
And now works all fine !!!
Thank you very much for the very fast support !!! 
The Fact is that the https://github.com/openhab/openhabian/releases new version 05.08.2019 has old Zwave / Zway / Zigbee … Versions, all of them have 2.4
But for me ist the Problem now solved.
Thanks all for Help!
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OpenHABian may default to the current stable release, which is currently 2.4. You can also choose testing or unstable releases though.
In fact I run OpenHABian with the latest testing release, 2.5M2.
Im new in all this OpenHab stuff. I will test the 2.5M2 now and watch, I have not deleted the other installation yet, maybe I have to go back to the 2.4 it will show up.
Now it only counts that it works, it has to be checked, if it can be linked and everything else before I buy some more.