Sonoff TH16 is not sending Temp to openhab

That has nothing to do with my code. The binding only subscribes to the mqtt broker so has no effect on it.
There was some “smart quotes”: “” and it should be:"" in the item

This is because you are not using the How to use code fences

Your item should be:

Number:Temperature Sonoff_Temp_Test "Temperature Sonoff [%.1f °C]" { mqtt="<[openmqtt:tele/Sonoff_Temp_1/SENSOR:state:JSONPATH($.DS18B20.Temperature)]" }