Yes it does ship with the right type of firmware but an older version so while it will work out-of-the-box it is still highly recommended that you update the firmware as latest will always contain more bug-fixes.
You can currently only use it with Zigbee2MQTT as the Zigbee binding does not yet support CC2652, see: https://discourse.openhab.org/t/discussion-about-texas-instruments-z-stack-3-0-and-cc2652-and-cc1352-zigbee-coordinator-adapters-with-openhab-zigbee-binding/129385
There is no automatic scan as the Zigbee radio is a serial device so regardless of Zigbee implementation you will always need to manually config it use to device path of the serial port that it has been assigned.